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• DüzeltmeAçık Erişim2026Scopus SJRQ2/r/kostu/10478
  Retraction Note: Synthesis of Bimetallic Nickel-Cobalt Nanoparticles Supported by Functional Multi-Walled Carbon Nanotubes by Chemical Methods: Characterization and Hydrogen Energy Generation (Topics in Catalysis, (2024), 67, 9-12, (606-614), 10.1007/s11244-024-01907-x)

  Zare, Najmeh; Karimi, Fatemeh; Altuner, Elif Esra; Mashkoor, Hussein; Tiri, Rima Nour Elhouda; Gulbagca, Fulya; Bijad, Majede; Cherif, Ali; Sen, Fatih

  The Editors-in-Chief have retracted this article because of errors and inconsistencies which raise concerns regarding the validity of the research reported in this work. A review conducted by the journal found that: The turnover frequency reported in the section entitled Catalytic Studies of Hydrogen Production was incorrectly calculated; There is no conclusive evidence that bimetallic Nickel-Cobalt nanoparticles associated with carbon nanotubes were synthesized, as the reported XRD pattern and TEM micrographs don’t support this result. Furthermore, the description of the synthesis procedure was considered to be lacking in substance; The differences between the average sizes of nanoparticles is not adequately explained. The authors were asked to comment on these concerns, but their explanation was deemed unsatisfactory. The Editors-in-Chief no longer have confidence in the research presented in this article. The authors disagree with this retraction.

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• MakaleAçık Erişim2025Scopus SJRQ2/r/kostu/10558
  Cobalt Nanoparticles Supported Active Carbon from Chitosan Biopolymer Using Thermal Method: Synthesis, Characterization, and Hydrogen Production

  Darabi, Rozhin; Karimi-Maleh, Hassan; Altuner, Elif Esra; Gulbagca, Fulya; Tiri, Rima Nour Elhouda; Chinnathambi, Arunachalam; Brindhadevi, Kathirvel; Halvaci, Ebru; Sen, Fatih

  Activated carbon based Cobalt nanoparticles (Co@AC NPs), considered in the context of hydrogen energy, which is a renewable and sustainable energy, were synthesized by the hydrothermal method, and their catalytic activities were tested. For this, hydrogen production tests were carried out with the help of sodium borohydride (NaBH4) methanolysis of Co@AC NPs synthesized by the thermal method. Ultraviolet–visible spectroscopy (UV–Vis), Fourier transmission spectroscopy (FTIR), transmission electron microscopy (TEM), and X-ray diffraction (XRD) characterization tests were performed. According to the TEM characterization result, it has been observed that the NPs have a spherical shape and an average size of 2.52 ± 0.92 nm. Then, using the catalytic studies, it was observed that hydrogen production’s reusability is found to be 86%. The activation energy (Ea), enthalpy (∆H), and entropy (∆S) values were found to be 20.28 kJ⋅mol−1, 17.74 kJ⋅mol−1, and −125.97 J⋅mol−1 K−1, respectively. The obtained values have yielded excellent results and guide future sustainable and renewable hydrogen energy studies by reducing costs, ensuring environmental sustainability by avoiding the formation of undesirable by-products, and producing hydrogen from NaBH4 through its high catalytic properties.

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  AtıfScopus5·WoS4·OpenAlex4

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• DüzeltmeYayıncıda açık erişim2025Scopus SJRQ2/r/kostu/10465
  Correction to: Cobalt Nanoparticles Supported Active Carbon from Chitosan Biopolymer Using Thermal Method: Synthesis, Characterization, and Hydrogen Production (Topics in Catalysis, (2024), 10.1007/s11244-024-01998-6)

  Darabi, Rozhin; Karimi-Maleh, Hassan; Altuner, Elif Esra; Gulbagca, Fulya; Tiri, Rima Nour Elhouda; Chinnathambi, Arunachalam; Brindhadevi, Kathirvel; Halvaci, Ebru; Sen, Fatih

  The Acknowledgements section was missing from this article and should have read, “This project was supported by Researchers Supporting Project number (RSP2024R383) King Saud University, Riyadh, Saudi Arabia” In this article, the e-mail address of the co-author Arunachalam Chinnathambi was incorrectly given as “arun.chin78@gmail.com” but should have been “carunachalam@ksu.edu.sa”.

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• DüzeltmeAçık Erişim2025Scopus SJRQ2/r/kostu/10460
  Retraction Note: Synthesis of Silver Nanoparticles by Biogenic Methods: Characterization and Development of a Sensor Sensible to Pharmaceutical Medicine Paracetamol (Topics in Catalysis, (2024), 67, 9-12, (585-593), 10.1007/s11244-023-01887-4)

  Karimi, Fatemeh; Altuner, Elif Esra; Aygun, Aysenur; Bayat, Ramazan; Rajendran, Saravanan; Sen, Fatih

  The Editors-in-Chief have retracted this article because of concerns regarding the validity of the research reported in this work. A review conducted by the journal found that the reported average crystalline size for silver nanoparticles (NPs) as determined by an analysis of the XRD intensity peaks (Fig. 3) is not consistent with the average size determined by TEM imaging (Fig. 4a), and that the former analysis was not adequately reported in the article. Furthermore, there is lack of agreement between the TEM result shown in Fig. 4 and the size distribution of NPs presented in the inset. The authors were asked to comment on these concerns, but their explanation was deemed unsatisfactory. The Editors-in-Chief no longer have confidence in the research presented in this article. The authors disagree with this retraction.

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• DüzeltmeAçık Erişim2025Scopus SJRQ2/r/kostu/10387
  Retraction note: Cobalt Nanoparticles Supported Active Carbon from Chitosan Biopolymer Using Thermal Method: Synthesis, Characterization, and Hydrogen Production (Topics in Catalysis, (2025), 68, 5-8, (540-549), 10.1007/s11244-024-01998-6)

  Darabi, Rozhin; Karimi‑Maleh, Hassan; Altuner, Elif Esra; Gulbagca, Fulya; Tiri, Rima Nour Elhouda; Chinnathambi, Arunachalam; Brindhadevi, Kathirvel; Halvaci, Ebru; Sen, Fatih

  Editors-in-Chief have retracted this article due to a compromised initial peer review process. A subsequent post-publication review revealed the following concerns: Misuse of the Eyring equation and incorrect interpretation of UV-vis spectroscopy data; A 50% discrepancy between the particle size determined by XRD and TEM that is not addressed in the paper; Multiple issues with Table 1, e.g., the values in the table do not seem to pertain to the same reaction, making comparison confusing; the table also equates “performance” with “activation energy.” Dubious reliability of certain citations. The Editors-in-Chief have therefore lost confidence in the results reported by this article. Fatih Sen, Hassan Karimi-Maleh, Rima Nour Elhouda Tiri, Fulya Gulbagca and Elif Esra Altuner disagree with this retraction. None of the remaining authors have responded to the correspondence from the Publisher about this retraction.

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• MakaleYalnız künye2024Scopus SJRQ2/r/kostu/10531
  Synthesis of Bimetallic Nickel-Cobalt Nanoparticles Supported by Functional Multi-Walled Carbon Nanotubes by Chemical Methods: Characterization and Hydrogen Energy Generation

  Zare, Najmeh; Karimi, Fatemeh; Altuner, Elif Esra; Mashkoor, Hussein; Tiri, Rima Nour Elhouda; Gulbagca, Fulya; Bijad, Majede; Cherif, Ali; Sen, Fatih

  In this study, nickel-cobalt@functionalized multi-walled carbon nanoparticles (NiCo@f-MWCNT NPs) were synthesized, analysed, and used for hydrogen generation via methanolysis on NaBH4. For the NPs synthesis, two steps were conducted (i.e., i: MWCNT was functionalized in an acid medium to support NPs (f-MWCNT); ii: NiCo NPs were synthesized and supplemented with f-MWCNT). Various characterization techniques were used to examine the morphological structure of NiCo@f-MWCNT NPs. The transmission electron microscope (TEM) results showed that the NPs were sized as 3.941 ± 1.094 nm with a spherical structure. The X-ray diffraction analysis (XRD) results indicated an average crystalline size of 1.46 nm. The evaluation of the catalytic performance for hydrogen production revealed that the turnover frequency (TOF) was calculated to be 2934.4 min− 1 with activation energy (Ea) and enthalpy (∆H) of 39.29 kJ/mol and 36.74 kJ/mol, respectively, which indicates high viability for hydrogen transport and generation application and processes.

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  AtıfScopus13·OpenAlex10

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• MakaleYalnız künye2024Scopus SJRQ2/r/kostu/10508
  Synthesis of Silver Nanoparticles by Biogenic Methods: Characterization and Development of a Sensor Sensible to Pharmaceutical Medicine Paracetamol

  Karimi, Fatemeh; Altuner, Elif Esra; Aygun, Aysenur; Bayat, Ramazan; Rajendran, Saravanan; Sen, Fatih

  In this study, silver nanoparticles (Ag NPs) were synthesized in biogenic methods. It is aimed to improve the electrochemical sensor efficiency of synthesized Ag NPs against the pharmaceutical drug paracetamol. For this purpose, fourier transmission infrared spectroscopy (FTIR), ultra-violet visible spectroscopy (Uv–vis), X-ray differentiation (XRD), and transmission electron spectroscopy (TEM) analyses were performed to elucidate the structure of the synthesized Ag NPs. In the TEM characterization results, the mean size of the NPs was found to be 19.035 nm using TEM characterization and the XRD results, the crystalline size of the NPs was 11.66 nm. Sensor studies were performed with cyclic voltammetry (CV) and differential pulse voltammetry (DPV) techniques. Paracetamol showed a sensitivity of approximately 0.4 V to Ag NPs in this study. The linear ranges of this study are 6.5–14.5 µM, with a limit of detection (LOD) of 5.79 µM and a limit of quantification (LOQ) of 17.56 µM.

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  AtıfScopus12·WoS7·OpenAlex11

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